white spots on children

If so, then what vitamin? Also is it a reaction to fluoride?
You don't mention which teeth - adult or child. I will guess at new upper front adult teeth.
White spots on the adult teeth are usually due to fluoride. It is a minor side-effect which is more than counterbalanced by the beneficial effects of the fluoride.
These spots developed when the teeth were forming (about first 2 years of life), and have absolutely no relation to current fluoride exposure, and certainly NO relation to vitamin "deficiency" either early in life or now.
Different people have slightly different degrees of blemishes ranging from nothing at all to white spots to brown spots. Unless it is particularly unsightly, no treatment is required or recommended.

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